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By taking samples at numerous study sites over extended periods of time, scientists have discovered that some contaminants travel entirely by air—these are what Frank Wania of the University of Toronto calls fliers. Some—the swimmers—stay in the water, circulating with ocean currents.
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Depending on temperature and weather conditions, as well as the size, shape, and the elements that make up the molecule, the same substance can be found dissolved in water, as a gas, or as a particle. The smaller the molecule, the more volatile it typically is, and therefore the more likely to be swept along with atmospheric currents as a gas. These gas phase molecules— the fliers—can move in several meters per second, making the trip from their points of origin to remote locations like the Arctic in days or weeks. At the opposite extreme, the waterborne swimmers can take years to reach the same destination.
The hoppers, intermediate-sized molecules that can move between gas, liquid, and particle phase, may take days, weeks, or even years to reach the Arctic after their initial release. These hoppers may be present in liquid water, but as temperatures warm they will evaporate to gas phase but then condense and return to join water when temperatures cool. Another major influence on the movement and deposition of persistent pollutants is precipitation. Put simply, the more it rains or snows the more likely these contaminants are to wash out of clouds and be deposited on land, lakes, rivers, and oceans.
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When present as aerosols, the contaminants may even accelerate precipitation as water droplets coalesce around the tiny solids. Whatever affects atmospheric and ocean circulation clearly plays an important role in where environmentally roving persistent pollutants end up. The big hemispheric wind and ocean patterns known as gyres and oscillations all play a part—as do more localized storm systems and currents. Other contaminants follow the same pathway north from Russia.
What happens once pollutants reach the far north is very much influenced by where there is ice. On the east side of Greenland and across the Greenland Sea on the remote Norwegian islands of Svalbard that reach all the way up to 80 degrees north—in the path of air and water currents coming off of Greenland and the European mainland—levels of PCBs, PBDEs, and perfluorinated compounds have been found to be particularly high. When pollutants are released within range of the Atlantic Gulf Stream or get picked up by northerly air currents that also blow east, North American pollutants can also be transported across the Atlantic toward Europe.
Similarly, air masses may travel a northeasterly path from Asia across the Pacific to North America.
Swimmers, Hoppers and Fliers: How Do Toxic Chemicals Move around the Planet?
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